Peak Performance, or why you see so many Mountains...

You may ask, why a scientist does include so many pictures of mountains (all from the Alps) on a scientific website. Well, there are several answers. The simplest is, I adore Mountaineering in all its facettes and I do see quite some analogy between serious Mountaineering and good Science:

  • To climb a serious peak, you have to be in shape, know what you are doing, get up early, are not allowed to be anxious and you need endurance and perseverance.
  • All of these are perfect ingredients to perform well in the Sciences...

In addition, my personal perception of 'Gas Phase Conditions' resembles closely the situation in the high alpine glacier region: Its cold, only little air and some of the exotic cations might feel well there...


Peak Performance - Science

A personal selection of the 10 'best' publications from our group. Naturally very subjective...

Synthesis and characterization of crystalline niobium and tantalum heptacarbonyl cations.” W. Unkrig, M. Schmitt, D. Kratzert, D. Himmel and I. Krossing*, Nature Chem. 2020, 12, 647–653.

 

Oxidative Fluorination of Cu/ZnO Methanol Catalysts. V. Dybbert, F. Klein, A. Schaadt, A. Hoffmann, E. Frei, E. Erdem, T. Ludwig, H. Hillebrecht, I. Krossing*, Angew. Chem., Int. Ed. 2019, 58, 12935-12939.

 

Basic Remarks on Acidity. V. Radtke, D. Himmel, B. Butschke, I. Krossing*, Angew. Chem., Int. Ed. 2018, 57, 4386-4411.

 

Inhibiting Polysulfide Shuttle in Lithium-Sulfur Batteries through Low-Ion-Pairing Salts and a Triflamide Solvent. A. Shyamsunder, W. Beichel, P. Klose, Q. Pang, H. Scherer, A. Hoffmann, G. K. Murphy, I. Krossing*, L. F. Nazar*, Angew. Chem., Int. Ed. 2017, 56, 6192-6197.

 

Cationic cluster formation versus disproportionation of low-valent indium and gallium complexes of 2,2’-bipyridine M. R. Lichtenthaler, F. Stahl, D. Kratzert, L. Heidinger, E. Schleicher, J. Hamann, D. Himmel, S. Weber, I. Krossing*, NATURE COMMUNICATIONS 2015 6:8288.

 

The protoelectric potential map (PPM): an absolute two-dimensional chemical potential scale for a global understanding of chemistry. V. Radtke, D. Himmel, K. Pütz, S. K. Goll, I. Krossing, Chem. Eur. J. 2014, 20, 4194–4211.

 

Crystal Structure Determination of the Nonclassical 2-Norbornyl Cation. F. Scholz, D. Himmel, F. W. Heinemann, P. v. R. Schleyer, K. Meyer*, I. Krossing*, Science 2013, 341, 62-64.

 

[P9]+[Al(ORF)4], the Salt of a Homopolyatomic Phosphorus Cation. T. Köchner, T. A. Engesser, H. Scherer, D. A. Plattner, A. Steffani, I. Krossing*; Angew. Chem. Int. Ed. 2012, 51, 6529–6531.

 

Why are Ionic Liquids liquid? A simple explanation based on lattice and solvation energies. J. Slattery, C. Daguenet, P. Dyson, I. Krossing*, H. Weingärtner, A. Oleinikova, J. Am. Chem. Soc. 2006, 128, 13427-13434.

 

The facile preparation of weakly coordinating anions: structure and characterisation of silver polyfluoroalkoxyaluminates Ag[Al(ORF)4], calculation of the alkoxide ion affinity. I. Krossing, Chem. Eur. J. 2001, 7, 490-502.

 

 

Peak Performance - Mountains

Personally selected list of favorite peaks climbed over the last 30 years...

Chimborazo, 6310 m, Ecuador

Cotopaxi, 5896 m, Ecuador

Misti, 5820 m, Peru

Pisco, 5750 m, Peru

Rucu Pichincha, 4766 m, Ecuador

Pico Espejo, 4765 m, Venezuela (no cable car)

Monte Rosa, Punta Margerita, 4554 m, Switzerland

Finsteraarhorn, 4274 m, Switzerland

Castor, 4223 m, Switzerland

Tajumulco, 4220 m, Guatemala

Strahlhorn, 4190 m, Switzerland

Djebel Toubkal, 4165 m, Marocco

Breithorn, 4164 m, Switzerland

Bishorn, 4153 m, Switzerland

Gran Paradiso, 4061 m, Italy

Piz Bernina, 4049 m, Switzerland

Hinter Fischerhorn, 4025 m, Switzerland

Acatenango, 3976 m, Guatemala

Äbeni Flue, 3961 m, Switzerland

Piz Palü, 3908 m, Switzerland

Königsspitze, 3860 m, Italy

Grünegghorn, 3860 m, Switzerland

Chirripo, 3819 m, Costa Rica

Großglockner, 3798 m, Austria

Pigne de Arolla, 3791 m, Switzerland

Wildspitze, 3770 m, Austria

Zufallspitzen, 3757 m, Italy

Weißkugel, 3741 m, Austria

Combin de Corbassière, 3716 m, Switzerland

Tournelon Blanc, 3707 m, Switzerland

Tete Blanche, 3706, Switzerland

Palon de la Mare, 3703 m, Italy

Balmhorn, 3697 m, Switzerland

Punta San Matteo, 3678 m, Italy

Petit Combin, 3663 m, Switzerland

Blümlisalphorn, 3661 m, Switzerland

Großvenediger, 3657 m, Austria

Hinter Brochkogel, 3623 m, Austria

Üssers Barrhorn, 3610 m, Switzerland

Galenstock, 3586 m, Switzerland

Adamello, 3539 m, Italy

Watzespitze, 3532 m, Austria

Pointe de Oren, 3523 m, Switzerland

Zuckerhütl, 3507 m, Austria

Schrankogel, 3497 m, Austria

Fluchtkogel, 3494 m, Austria

Care Alto, 3465 m, Italy

Piz Corvatsch, 3451 m, Switzerland (no cable car)

Piz d'Err, 3378 m, Switzerland

Pico Veleta, 3367 m, Spain

Piz Buin, 3312 m, Switzerland

Piz Basodino, 3272 m, Switzerland

Clariden, 3267 m, Switzerland

Dents de Midi, Haute Cime, 3258 m, Switzerland

Signalhorn, 3207 m, Switzerland

Dreiländerspitze, 3197 m, Austria

Parseierspitze, 3036 m, Austria

Zugspitze, 2963 m, Germany

Brunnistock, 2952 m, Switzerland

Hochkönig, 2941 m, Austria

Birkkarspitze, 2749 m, Austria

Kaltwasserkarspitze, 2733 m, Austria

Watzmann, 2713 m, Germany

Profitis Ilias, 2404 m, Greece

Daltinden, 1533 m, Norway

Tafeltinden, 1395 m, Norway

...